2022 vol 1 issue 1
Review
Michał Baranowski1, Mateusz Dyksik1, Paulina Płochocka1,2*
(1) Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland(2) Laboratoire National des Champs Magnétiques Intenses, EMFL, CNRS UPR 3228, Université Grenoble Alpes, Université Toulouse, Université Toulouse 3, INSA-T, Grenoble and Toulouse, France
Correspondence to: paulina.plochocka@lncmi.cnrs.fr
Pages 3-25
https://doi.org/10.58332/v22i1a01
Abstract
Two-dimensional (2D) metal halide perovskites are natural quantum wells which consist of low bandgap metal-halide slabs, surrounded by organic spacers barriers. The quantum and dielectric confinements provided by the organic part lead to the extreme exciton binding energy which results in a huge enhancement of exciton fine structure in this material system. This makes 2D perovskites a fascinating playground for fundamental excitonic physics studies. In this review, we summarize the current understanding and quantification of the exciton fine structure in 2D perovskites. We discuss what is the role of exciton fine structure in the optical response of 2D perovskites and how it challenges our understanding of this fundamental excitation. Finally, we highlight some controversy related to particularly large bright-dark exciton states splitting and high efficiency of light emission from these materials. This can result from the unique synergy of excitonic and mechanical properties of 2D perovskites crystals.
Keywords
2D perovskites, exciton, fine structure, dark exciton states
First published: 18.11.2022